JEE Advanced levelSingle correct optionDifficulty 3 of 3pn105
Pyrosulphuric acid, HX2SX2OX7, is drawn with two S=O bonds on each S atom, two S-OH groups and one S-O-S bridge. The total number of sigma bonds in one molecule is
A12
B8
C14
D10
Answer: D
Each S is bonded to four O atoms: S-O sigma bonds total 4 + 4 = 8, counting the bridging oxygen twice (once for each S). Add 2 O-H bonds: 8 + 2 = 10 sigma bonds. The extra bonds in S=O are pi bonds.