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JEE Advanced levelSingle correct optionDifficulty 3 of 3pn105

Pyrosulphuric acid, , is drawn with two S=O bonds on each S atom, two S-OH groups and one S-O-S bridge. The total number of sigma bonds in one molecule is

  1. A12
  2. B8
  3. C14
  4. D10

Answer: D

Each S is bonded to four O atoms: S-O sigma bonds total 4 + 4 = 8, counting the bridging oxygen twice (once for each S). Add 2 O-H bonds: 8 + 2 = 10 sigma bonds. The extra bonds in S=O are pi bonds.
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