JEE Advanced levelSingle correct optionDifficulty 3 of 3pn102
One mole of PX4OX10 and one mole of PX4OX6 are separately treated with excess water, and each product is completely neutralised with NaOH (all replaceable hydrogens). The ratio of moles of NaOH used for PX4OX10 : PX4OX6 is
A1 : 1
B2 : 1
C3 : 2
D5 : 3
Answer: C
PX4OX10+6HX2O4HX3POX4 (tribasic): 4 x 3 = 12 mol NaOH. PX4OX6+6HX2O4HX3POX3 (dibasic): 4 x 2 = 8 mol NaOH. Ratio = 12 : 8 = 3 : 2.