JEE Main levelOne or more correct optionsDifficulty 2 of 3pb172
Select the correct statement(s) about boric acid.
AOn heating to about 370 K it forms metaboric acid, HBOX2.
BIn water its acidity arises from formation of [B(OH)X4]X− by accepting OHX−.
CSolid HX3BOX3 has a layered structure in which planar B(OH)X3 units are joined by hydrogen bonds.
DIt is a tribasic Bronsted acid because it has three OH groups, and so forms three series of sodium salts by direct neutralisation.
Answer: A, B, C
The layered hydrogen-bonded structure, loss of water to HBOX2 near 370 K, and the Lewis acid mode B(OH)X3+HX2O[B(OH)X4]X−+HX+ are all correct. The OH groups are not ionised as protons, so it is monobasic, and the fourth statement is false.