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MolSynapse / Question bank / p-Block Elements: Groups 13 and 14 / Boron compounds: diborane, boric acid, borax, boron halides
JEE Main levelSingle correct optionDifficulty 2 of 3pb171

The correct order of Lewis acid strength of boron trihalides towards a given base (such as ) is

  1. A
  2. B
  3. C
  4. D

Answer: B

Back donation of the halogen lone pair into the empty orbital of boron is - overlap. It is strongest for (same period, similar size), and falls on moving to Cl and Br. Less back donation leaves boron more electron deficient, so the acid strength is .
Practice p-Block Elements: Groups 13 and 14 More on Boron compounds: diborane, boric acid, borax, boron halides

More questions on Boron compounds: diborane, boric acid, borax, boron halides