JEE Advanced levelSingle correct optionDifficulty 3 of 3pb158
Beryl contains the cyclic silicate anion SiX6OX18X12− in which every SiOX4 tetrahedron shares exactly two corners with neighbours. The number of non-bridging (terminal) oxygen atoms in the ring is
A12
B6
C18
D24
Answer: A
Each of the 6 tetrahedra has 2 shared corners, each oxygen is shared by two tetrahedra, so bridging O =6×2/2=6. Terminal O =18−6=12, which matches the charge −12 (one negative charge per terminal O).