JEE Advanced levelSingle correct optionDifficulty 3 of 3pb160
A zeolite has the unit-cell composition NaX12[(AlOX2)X12(SiOX2)X12]⋅27HX2O. If all its NaX+ ions are exchanged by CaX2+ ions from hard water, the number of CaX2+ ions taken per unit cell is
A3
B12
C6
D24
Answer: C
The framework charge is −12 (one per Al). Twelve NaX+ carry +12; to keep charge balance each CaX2+ replaces two NaX+, so 12/2=6CaX2+ ions.