JEE Advanced levelOne or more correct optionsDifficulty 3 of 3pb071
Which of the following statements about carbon monoxide are correct?
AIt is an acidic oxide that dissolves in water to give carbonic acid.
BIt reduces FeX2OX3 to iron in the blast furnace.
CIt combines with nickel to form the volatile, tetrahedral Ni(CO)X4.
DIt is poisonous because it binds haemoglobin more strongly than OX2 does.
Answer: B, C, D
CO is a neutral oxide and does not form carbonic acid, so the first statement is false. In the blast furnace FeX2OX3+3CO2Fe+3COX2. Nickel and CO give volatile tetrahedral Ni(CO)X4 (Mond process). CO forms carboxyhaemoglobin, which is more stable than oxyhaemoglobin. Statements 2, 3 and 4 are correct.