JEE Main levelNumerical answerDifficulty 2 of 3pb033
Diborane hydrolyses completely according to BX2HX6+6HX2O2HX3BOX3+6HX2. Calculate the volume of hydrogen, in litres at STP, produced from 8.4g of BX2HX6. Take B=11, H=1 and molar volume =22.4L/mol. Give the answer to two decimal places.
Numerical answer type, answer in L, tolerance 0.01.
Answer: 40.32 L
Molar mass of BX2HX6=2(11)+6(1)=28g/mol, so n=8.4/28=0.30mol. The equation gives 6 mol HX2 per mol BX2HX6, so n(HX2)=1.80mol. V=1.80×22.4=40.32L.