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JEE Main levelSingle correct optionDifficulty 2 of 3o3022

Match the carbocations in List I with the main stabilising factor in List II. List I: (P) ; (Q) ; (R) ; (S) . List II: (1) donation of an oxygen lone pair into the empty p orbital; (2) delocalisation of charge into an aromatic ring; (3) delocalisation over two carbons through an adjacent C=C; (4) hyperconjugation with nine C-H bonds.

  1. AP-4, Q-1, R-2, S-3
  2. BP-4, Q-1, R-3, S-2
  3. CP-1, Q-4, R-2, S-3
  4. DP-2, Q-1, R-4, S-3

Answer: A

is stabilised by hyperconjugation with nine C-H bonds (P-4). is stabilised by the oxygen lone pair (Q-1). The benzyl cation is delocalised into the ring (R-2), and the allyl cation shares charge over two carbons through the C=C (S-3).
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