JEE Main levelSingle correct optionDifficulty 2 of 3o1077
Acetaldehyde is treated with (i) NaCN / HX2SOX4 (aq, cold); (ii) HX3OX+, heat. The final product is
A3-hydroxypropanoic acid
B2-hydroxypropanoic acid (lactic acid)
Cpropanoic acid
D2-oxopropanoic acid
Answer: B
CNX− adds to CHX3CHO to give the cyanohydrin CHX3CH(OH)CN. Acid hydrolysis of the nitrile converts −CN to −COOH, leaving the OH untouched: CHX3CH(OH)COOH.