JEE Main levelSingle correct optionDifficulty 2 of 3o1079
The rate of cyanohydrin formation from acetone and HCN is very small in pure HCN but increases when a few drops of NaOH are added; it falls again if strong acid is added. This is because
Abase converts acetone to its enol which attacks HCN
Bbase increases the concentration of the nucleophile CNX− and acid suppresses it
Cbase protonates the carbonyl oxygen and acid generates CNX−
Dacid catalyses direct attack of molecular HCN on carbon
Answer: B
HCN is a weak acid (pKa about 9) and a poor nucleophile. Base generates CNX−, the real nucleophile, while acid pushes the equilibrium HCNHX++CNX− back, lowering [CNX−] and the rate.