JEE Main levelSingle correct optionDifficulty 2 of 3o1075
The cyclic acetal formed from cyclohexanone and ethylene glycol is stable towards which of the following?
Adilute aqueous HX2SOX4, warm
Baqueous HCl, warm
Caqueous NaOH, warm
DHX3OX+ at room temperature, long standing
Answer: C
Acetals are ethers and are inert to bases and nucleophiles, but hydrolyse readily in aqueous acid through the oxocarbenium ion. Hence only the basic medium leaves the protecting group intact.