JEE Advanced levelOne or more correct optionsDifficulty 3 of 3nc182
On reduction with LiAlHX4 (followed by water), which of the following give a PRIMARY amine?
ACHX3CON(CHX3)X2
BCX6HX5NOX2
CCHX3CONHX2
DCHX3CHX2CN
Answer: C, D
The nitrile gives CHX3CHX2CHX2NHX2 and acetamide gives CHX3CHX2NHX2, both primary. The N,N-dimethylamide gives the tertiary amine CHX3CHX2N(CHX3)X2, and nitrobenzene gives azobenzene with LiAlH4.