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NEET levelSingle correct optionDifficulty 1 of 3nc094

Aniline reacts with excess water to give

  1. A4-bromoaniline only
  2. B3-bromoaniline only
  3. C3,5-dibromoaniline
  4. D2,4,6-tribromoaniline as a white precipitate

Answer: D

The group strongly activates the ortho and para positions, so bromination in water (no Lewis acid) goes to completion at all three positions, giving a white precipitate of 2,4,6-tribromoaniline.
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