JEE Main levelSingle correct optionDifficulty 2 of 3nc098
Electrolytic reduction of nitrobenzene in strongly acidic medium finally gives
A4-aminophenol
Baniline
Cazoxybenzene
D3-aminophenol
Answer: A
In strong acid, the first-formed N-phenylhydroxylamine rearranges (Bamberger rearrangement), with water attacking the para position. The product is 4-aminophenol, HO−CX6HX4−NHX2.