MolSynapsequestion bank
MolSynapse / Question bank / Amines and Aromatic Nitrogen Compounds / Nitrobenzene and aniline chemistry
JEE Main levelSingle correct optionDifficulty 2 of 3nc098

Electrolytic reduction of nitrobenzene in strongly acidic medium finally gives

  1. A4-aminophenol
  2. Baniline
  3. Cazoxybenzene
  4. D3-aminophenol

Answer: A

In strong acid, the first-formed N-phenylhydroxylamine rearranges (Bamberger rearrangement), with water attacking the para position. The product is 4-aminophenol, .
Practice Amines and Aromatic Nitrogen Compounds More on Nitrobenzene and aniline chemistry

More questions on Nitrobenzene and aniline chemistry