JEE Advanced levelSingle correct optionDifficulty 3 of 3mc214
A mixture of 1.0molHX2 and 1.0molOX2 is sparked so that 2HX2+OX22HX2O goes to completion. Water remains as vapour at the final temperature. The average molar mass of the final gaseous mixture is (H = 1, O = 16)
A22.67gmol−1
B17.00gmol−1
C32.00gmol−1
D25.00gmol−1
Answer: A
H2 is limiting: 1.0 mol H2 uses 0.5 mol O2 and gives 1.0 mol H2O(g); 0.5 mol O2 is left. Final gas: 1.0 mol H2O (18 g) + 0.5 mol O2 (16 g) = 34 g in 1.5 mol. Average M = 34/1.5 = 22.67 g/mol.