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JEE Advanced levelSingle correct optionDifficulty 3 of 3mc214

A mixture of and is sparked so that goes to completion. Water remains as vapour at the final temperature. The average molar mass of the final gaseous mixture is (H = 1, O = 16)

  1. A
  2. B
  3. C
  4. D

Answer: A

H2 is limiting: 1.0 mol H2 uses 0.5 mol O2 and gives 1.0 mol H2O(g); 0.5 mol O2 is left. Final gas: 1.0 mol H2O (18 g) + 0.5 mol O2 (16 g) = 34 g in 1.5 mol. Average M = 34/1.5 = 22.67 g/mol.
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