JEE Advanced levelSingle correct optionDifficulty 3 of 3mc213
10.0L of a mixture of CO and COX2 at STP has a vapour density of 17. It is passed through excess KOH solution, which absorbs only COX2. The volume of gas that remains at STP is (C = 12, O = 16)
A3.75L
B6.25L
C5.00L
D7.50L
Answer: B
M(mix) = 34. With x = mole (volume) fraction of CO2: 44x + 28(1 - x) = 34, so x = 0.375. CO2 = 3.75 L is absorbed; CO left = 10.0 - 3.75 = 6.25 L.