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JEE Advanced levelSingle correct optionDifficulty 3 of 3mt192

1200 g of crude zirconium containing 95.0% Zr (rest oxide and nitride impurities that do not react with iodine) is heated with iodine in the van Arkel process, . With Zr = 91 and I = 127, the mass of that combines with the zirconium in one complete conversion is

  1. A3182 g
  2. B6699 g
  3. C1591 g
  4. D6364 g

Answer: D

n(Zr) = 0.950 x 1200/91 = 12.527 mol. Each Zr needs 2 mol of (M = 254 g/mol), so n() = 25.055 mol. Mass = 25.055 x 254 = 6364 g. In practice the iodine is regenerated at the filament and recycled.
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More questions on Refining methods: zone refining, van Arkel, Mond process, electrolytic refining