JEE Advanced levelSingle correct optionDifficulty 3 of 3mt192
1200 g of crude zirconium containing 95.0% Zr (rest oxide and nitride impurities that do not react with iodine) is heated with iodine in the van Arkel process, Zr+2IX2ZrIX4. With Zr = 91 and I = 127, the mass of IX2 that combines with the zirconium in one complete conversion is
A3182 g
B6699 g
C1591 g
D6364 g
Answer: D
n(Zr) = 0.950 x 1200/91 = 12.527 mol. Each Zr needs 2 mol of IX2 (M = 254 g/mol), so n(IX2) = 25.055 mol. Mass = 25.055 x 254 = 6364 g. In practice the iodine is regenerated at the filament and recycled.