JEE Main levelSingle correct optionDifficulty 2 of 3mt171
In the Mond process the volatile carbonyl is formed and decomposed respectively at about
A330-350 K and 330-350 K, using electrolysis for decomposition
B330-350 K and 450-470 K
C450-470 K and 330-350 K
D800 K and 1200 K
Answer: B
Formation of Ni(CO)X4 is exothermic with a decrease in moles of gas, so it is favoured at low temperature (330-350 K). The reverse reaction is favoured at 450-470 K and gives pure nickel.