JEE Advanced levelSingle correct optionDifficulty 3 of 3mt145
At 1500K the standard Gibbs energies of formation of oxides per mole of OX2 are: 34Al+OX232AlX2OX3, −820kJ; 2Fe+OX22FeO, −380kJ. Using these data, ΔG∘ at 1500K for 3FeO+2AlAlX2OX3+3Fe is
A−440kJ
B−660kJ
C−1230kJ
D−1800kJ
Answer: B
The reaction uses 1.5 mol of OX2 equivalents. Multiply the aluminium line by 1.5 to get −1230kJ, and reverse the iron line scaled by 1.5 to get +570kJ. The sum is −1230+570=−660kJ, so aluminium reduces FeO spontaneously.