$194\mathrm{kg}$ of a zinc ore containing $60.0\%$ $\mathrm{ZnS}$ is roasted completely to $\mathrm{ZnO}$ ($2\mathrm{ZnS}+3\mathrm{O}{}_2\to 2\mathrm{ZnO}+2\mathrm{SO}{}_2$). The oxide is leached with dilute acid, $\mathrm{ZnO}+\mathrm{H}{}_2\mathrm{SO}{}_4\to \mathrm{ZnSO}{}_4+\mathrm{H}{}_2\mathrm{O}$, with $95.0\%$ of the oxide dissolving. Electrowinning then deposits $90.0\%$ of the dissolved zinc as metal. With $\mathrm{Zn}=65$, $\mathrm{S}=32$, $\mathrm{O}=16$, $\mathrm{H}=1$, the mass of $\mathrm{H}{}_2\mathrm{SO}{}_4$ consumed in leaching and the mass of zinc deposited are

1. A117.60 kg and 66.69 kg
2. B111.72 kg and 74.10 kg
3. C111.72 kg and 66.69 kg
4. D223.44 kg and 66.69 kg