Answer: D
The compound is 3-ethyl-2-methylpentane. The longest chain is pentane (5 C), with ethyl at C3 and methyl at C2. Prefixes are arranged alphabetically (ethyl before methyl). Choosing the isopropyl-bearing 3-carbon branch as a substituent on pentane (3-isopropylpentane) fails the rule of selecting the chain with the most substituents.