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JEE Advanced levelSingle correct optionDifficulty 3 of 3nm212

Of the nine structural isomers of heptane, , how many contain a quaternary carbon (a carbon bonded to four other carbon atoms)?

  1. A3
  2. B1
  3. C2
  4. D4

Answer: A

Place a carbon with four C neighbours: 2,2-dimethylpentane, 3,3-dimethylpentane and 2,2,3-trimethylbutane. 2,2-Dimethylpentane has one quaternary C, as do the other two; none of the nine has two. Total 3.
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