JEE Advanced levelSingle correct optionDifficulty 3 of 3nm212
Of the nine structural isomers of heptane, CX7HX16, how many contain a quaternary carbon (a carbon bonded to four other carbon atoms)?
A3
B1
C2
D4
Answer: A
Place a carbon with four C neighbours: 2,2-dimethylpentane, 3,3-dimethylpentane and 2,2,3-trimethylbutane. 2,2-Dimethylpentane has one quaternary C, as do the other two; none of the nine has two. Total 3.