JEE Advanced levelNumerical answerDifficulty 3 of 3ig155
A mixture of CHX4 (16) and CX2HX6 (30) has a density of 1.050gL−1 at 300K and 1.00atm. Taking R=0.0821LatmK−1mol−1, the mole percent of CX2HX6 (one decimal) is
Numerical answer type, answer in %, tolerance 0.2.
Answer: 70.4 %
Mˉ=dRT/P=1.050×0.0821×300=25.86gmol−1. 16(1−x)+30x=25.86, x=1425.86−16=0.7044, i.e. 70.4 mole percent.