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Ozonolysis and oxidative cleavage
JEE Main level
Single correct option
Difficulty 2 of 3
hc040
2-Methylbut-2-ene is ozonised and the ozonide is worked up with
H
X
2
O
X
2
(oxidative work-up). The products are
A
propanone and ethanal
B
propanal and ethanoic acid
C
propanone and ethanoic acid
D
butanone and methanoic acid
Answer: C
(
CH
X
3
)
X
2
C
=
CH
−
CH
X
3
is cleaved into
(
CH
X
3
)
X
2
C
=
O
(a ketone, unchanged) and
CH
X
3
CHO
. Hydrogen peroxide oxidises the aldehyde to
CH
X
3
COOH
.
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