JEE Advanced levelSingle correct optionDifficulty 3 of 3hx161
Chlorobenzene is nitrated with HNOX3/HX2SOX4 and the major (para) product is separated, heated with aqueous NaOH at 433 K and finally acidified. The product is
A3-nitrophenol
B4-chlorophenol
C2-nitrophenol
D4-nitrophenol
Answer: D
Nitration gives mainly 1-chloro-4-nitrobenzene. The para NOX2 activates Cl for SNAr, so OHX− displaces Cl to give sodium 4-nitrophenoxide; acidification gives 4-nitrophenol. The NOX2 group is not removed.