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JEE Advanced levelSingle correct optionDifficulty 3 of 3hx161

Chlorobenzene is nitrated with / and the major (para) product is separated, heated with aqueous at 433 K and finally acidified. The product is

  1. A3-nitrophenol
  2. B4-chlorophenol
  3. C2-nitrophenol
  4. D4-nitrophenol

Answer: D

Nitration gives mainly 1-chloro-4-nitrobenzene. The para activates for SNAr, so displaces to give sodium 4-nitrophenoxide; acidification gives 4-nitrophenol. The group is not removed.
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