JEE Main levelSingle correct optionDifficulty 2 of 3hx118
Direct iodination of benzene with IX2 alone gives very poor yields of iodobenzene, but the yield is good when a little conc. HNOX3 is added. The role of HNOX3 is to
Aconvert benzene to nitrobenzene which is iodinated faster
Bact as a Lewis acid catalyst for IX2
Coxidise the HI formed, which would otherwise reduce iodobenzene back to benzene
Dreduce IX2 to IX−
Answer: C
CX6HX6+IX2CX6HX5I+HI is reversible and HI is a strong reducing agent. An oxidising agent such as HNOX3 removes HI by oxidising it to IX2, which shifts the equilibrium towards iodobenzene.