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JEE Main levelSingle correct optionDifficulty 2 of 3hx116

Fluorobenzene can be prepared from aniline by diazotisation followed by

  1. Atreatment with powder and (Gattermann reaction)
  2. Btreatment with and then heating the isolated
  3. Cheating with and (Sandmeyer reaction)
  4. Dtreatment with aqueous at 273 K

Answer: B

Fluorine is introduced by the Balz-Schiemann reaction: benzenediazonium chloride is converted into the insoluble diazonium tetrafluoroborate, which on gentle heating loses and to give . Aqueous fluoride does not displace cleanly, and Sandmeyer/Gattermann conditions are used for and .
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