Toluene is converted to C6H5CH2Cl and to a mixture of o-ClC6H4CH3 and p-ClC6H4CH3 under two different sets of conditions

Question

Toluene is converted to C6H5CH2Cl and to a mixture of o-ClC6H4CH3 and p-ClC6H4CH3 under two different sets of conditions. The correct pairing is

Accepted Answer

Cl2 with light on boiling toluene gives the benzyl chloride; Cl2 with FeCl3 in the dark gives the ring chlorides

Answer

Cl2 with FeCl3 gives the benzyl chloride; Cl2 with light gives the ring chlorides

Answer

Cl2 with light gives the ring chlorides; Cl2 with FeCl3 gives m-chlorotoluene

Answer

Cl2 with FeCl3 gives both the benzyl chloride and the ring chlorides in equal amounts

Toluene is converted to $C X_{6} H X_{5} CH X_{2} Cl$ and to a mixture of $o - ClC X_{6} H X_{4} CH X_{3}$ and $p - ClC X_{6} H X_{4} CH X_{3}$ under two different sets of conditions. The correct pairing is