JEE Main levelSingle correct optionDifficulty 2 of 3hx028
For the reaction CHX3CHX2Br+CNX−CHX3CHX2CN+BrX− at the same temperature and concentrations, the rate is highest in
Amethanol
Bdimethyl sulfoxide (DMSO)
Cethanol
Dwater
Answer: B
This is an SN2 reaction of an anionic nucleophile. Polar protic solvents (water, alcohols) hydrogen-bond to CNX− and lower its reactivity; polar aprotic DMSO solvates only the cation, leaving a very reactive nucleophile.