MolSynapsequestion bank
MolSynapse / Question bank / General Organic Chemistry III: Reaction Intermediates / Stability ranking of drawn radicals, carbanions and carbenes
JEE Main levelSingle correct optionDifficulty 2 of 3g3242

Which statement about the ground state of the species shown is correct?

  1. AIt is linear with sp hybridisation and a filled p orbital.
  2. BIt is a triplet with two unpaired electrons of parallel spin in different orbitals, and the H-C-H angle is about .
  3. CIt is a singlet with one filled sp orbital and one empty p orbital.
  4. DIt is a carbanion with a lone pair and a negative charge.

Answer: B

The species shown is methylene, , the simplest carbene. With no stabilising substituents the triplet state, with one electron in each of two nearly degenerate orbitals and parallel spins, lies lower than the singlet by about 9 kcal/mol. The triplet is bent with an H-C-H angle near .
Practice General Organic Chemistry III: Reaction Intermediates More on Stability ranking of drawn radicals, carbanions and carbenes

More questions on Stability ranking of drawn radicals, carbanions and carbenes