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General Organic Chemistry III: Reaction Intermediates
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Reaction energy profiles, kinetic vs thermodynamic control
JEE Main level
Single correct option
Difficulty 2 of 3
g3193
A reaction has
E
a
=
60.0
kJ
mo
l
−
1
(
R
=
8.314
J
mo
l
−
1
K
−
1
). The ratio
k
(
310
K
)
/
k
(
300
K
)
is closest to
A
4.7
B
1.1
C
0.46
D
2.2
Answer: D
ln
(
k
2
/
k
1
)
=
(
E
a
/
R
)
(
1/
T
1
−
1/
T
2
)
=
(
60000/8.314
)
(
1/300
−
1/310
)
=
0.776
. So
k
2
/
k
1
=
2.17
, i.e. about 2.2.
Practice General Organic Chemistry III: Reaction Intermediates
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