JEE Main levelSingle correct optionDifficulty 2 of 3g3190
On warming, 3-bromobut-1-ene and 1-bromobut-2-ene interconvert in a polar medium. The common species through which they interconvert is
Aa free carbene
Ba cyclic bromonium ion with no allylic delocalisation
Cthe resonance-stabilised allylic cation CHX3−CH−CH−CHX2 (+ charge delocalised) formed by ionisation of C−Br
Da localised carbanion formed by loss of HX+
Answer: C
Ionisation of the C−Br bond in either adduct gives the same allylic cation, which recombines with BrX− at either terminus. This reversibility lets equilibrium (thermodynamic) control operate.