Answer: D
In the monoanion, the phenolic OH hydrogen-bonds to the carboxylate oxygen through a six-membered chelate ring. This stabilises the monoanion, so the first ionisation is easy (pKa 2.97, stronger than the para isomer at 4.54). The same stabilisation makes removal of the phenolic proton difficult, so pKa2 is about 13.6, much more than phenol (10.0).