JEE Advanced levelSingle correct optionDifficulty 3 of 3g2212
50.0mL of 0.100MHClOX4 and 50.0mL of 0.300MHNOX3 are mixed in water. Treating both as completely ionised (levelled to HX3OX+), the pH of the mixture is
A0.40
B1.00
C0.70
D0.52
Answer: C
Total HX3OX+ moles =50.0×0.100+50.0×0.300=20.0mmol in 100.0mL, so [HX3OX+]=0.200M. pH=−log0.200=0.70. The value 0.40 comes from forgetting to dilute, and 1.00 from using only the HClOX4 concentration.