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NEET levelSingle correct optionDifficulty 1 of 3g1249

Loss of a hydride ion from a C-H bond of the compound shown can give two different carbocations. The one formed preferentially is

  1. Athe primary cation, because it is the least hindered
  2. Bthe tertiary cation, stabilised by the +I effect and hyperconjugation of three methyl groups
  3. Ca secondary cation, because it is intermediate
  4. Dboth cations equally

Answer: B

The compound shown is isobutane. Removal of H- from the CH carbon gives a tertiary cation, stabilised by the +I effect and hyperconjugation of three methyl groups. Removal from a CH3 gives a primary cation, which is much less stable.
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