JEE Main levelSingle correct optionDifficulty 2 of 3eq098
A 0.900g aspirin tablet (acetylsalicylic acid, CX9HX8OX4, molar mass 180) is boiled with 50.0mL of 0.500MNaOH, which neutralises and hydrolyses it (2 mol NaOH per mol aspirin). The excess NaOH needs 30.4mL of 0.500MHCl. The mass percent of aspirin in the tablet is
A500.0%
B196.0%
C98.0%
D49.0%
Answer: C
NaOH taken = 0.0500 x 0.500 = 0.0250 mol; excess = 0.0304 x 0.500 = 0.0152 mol; consumed = 0.0098 mol. Aspirin = 0.0098/2 = 0.0049 mol = 0.882 g. Percent = 0.882/0.900 x 100 = 98.00%.