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JEE Main levelSingle correct optionDifficulty 2 of 3eq098

A aspirin tablet (acetylsalicylic acid, , molar mass ) is boiled with of , which neutralises and hydrolyses it (2 mol per mol aspirin). The excess needs of . The mass percent of aspirin in the tablet is

  1. A500.0%
  2. B196.0%
  3. C98.0%
  4. D49.0%

Answer: C

NaOH taken = 0.0500 x 0.500 = 0.0250 mol; excess = 0.0304 x 0.500 = 0.0152 mol; consumed = 0.0098 mol. Aspirin = 0.0098/2 = 0.0049 mol = 0.882 g. Percent = 0.882/0.900 x 100 = 98.00%.
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