JEE Main levelSingle correct optionDifficulty 2 of 3eq096
A water sample contains 97.2mg/L of Ca(HCOX3)X2 (molar mass 162) and 60mg/L of MgSOX4 (molar mass 120). Hardness is expressed as ppm of CaCOX3 (molar mass 100). The permanent hardness is
A81 ppm
B110 ppm
C60 ppm
D50 ppm
Answer: D
Ca(HCO3)2 = 97.2/162 = 0.60 mmol/L (temporary hardness = 60 ppm). MgSO4 = 60/120 = 0.50 mmol/L, which is not removed by boiling, so permanent hardness = 0.50 x 100 = 50 ppm (total 110 ppm).