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JEE Advanced levelSingle correct optionDifficulty 3 of 3eq070

A mixture contains mol of and mol of . Assuming only and oxalate are oxidised, the moles of required in acid are

  1. A0.1 mol
  2. B0.14 mol
  3. C0.08 mol
  4. D0.12 mol

Answer: D

Fe2+ comes only from FeC2O4: 0.100 mol, giving 0.100 mol electrons. Oxalate = 0.100 + 3 x 0.0500 = 0.250 mol, giving 0.500 mol electrons. Total = 0.600 mol e-, and KMnO4 = 0.600/5 = 0.120 mol.
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