NEET levelSingle correct optionDifficulty 1 of 3ec208
During the conductometric titration of HCl against NaOH, the conductance decreases before the end point because
AHX+ ions of high mobility are replaced by NaX+ ions of much lower mobility
Bthe number of ClX− ions in the solution decreases
Cthe water formed in the reaction dilutes the solution appreciably
DNaX+ ions have higher mobility than HX+ ions
Answer: A
HX++OHX−HX2O removes one HX+ for every NaX+ added, so the total number of ions stays constant while HX+ (λ∘≈350Scm2mol−1) is exchanged for NaX+ (λ∘≈50). The ClX− count does not change, and the water formed is negligible compared with the solvent. NaX+ is much less mobile than HX+, so (D) is the reverse of the truth.