NEET levelSingle correct optionDifficulty 1 of 3ec191
According to Kohlrausch's law of independent migration of ions, at infinite dilution
Aeach ion makes a definite contribution to Λm∘ of the electrolyte, independent of the nature of the other ion present
Bthe molar conductivity of every electrolyte becomes zero
Cthe conductivity of all electrolytes becomes equal
Dthe molar conductivity varies linearly with c
Answer: A
Kohlrausch's law states Λm∘=ν+λ+∘+ν−λ−∘: at infinite dilution the ions move independently and each has a characteristic limiting conductivity. At infinite dilution Λm reaches its maximum value Λm∘, not zero (it is κ that tends to zero). Linear variation with c is the Debye-Huckel-Onsager equation, not Kohlrausch's law.