JEE Main levelSingle correct optionDifficulty 2 of 3ec195
The limiting molar ionic conductivities of AlX3+ and SOX4X2− are 189 and 160Scm2mol−1 respectively. The limiting equivalent conductivity of AlX2(SOX4)X3, in Scm2eq−1, is
A143
B858
C349
D174.5
Answer: A
By Kohlrausch's law, Λm∘(AlX2(SOX4)X3)=2λ∘(AlX3+)+3λ∘(SOX4X2−)=2(189)+3(160)=858Scm2mol−1. The n-factor of AlX2(SOX4)X3 is 6, so Λeq∘=858/6=143Scm2eq−1. Adding the two ionic values once gives 349, which ignores the stoichiometry.