JEE Advanced levelNumerical answerDifficulty 3 of 3ec180
The molar conductivity of a 0.050M solution of a strong electrolyte is 40.0Scm2mol−1. In a conductivity cell whose parallel electrodes each have area 1.50cm2, this solution shows a resistance of 360Ω. The distance between the electrodes, in cm (two decimals), is
Numerical answer type, answer in cm, tolerance 0.02.
Answer: 1.08 cm
First recover the conductivity: κ=Λmc/1000=40.0×0.050/1000=2.0×10−3Scm−1. Cell constant G∗=κR=2.0×10−3×360=0.72cm−1. Since G∗=l/A, l=0.72×1.50=1.08cm.