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JEE Main levelOne or more correct optionsDifficulty 2 of 3ec170

Which of the following would increase the rate of rusting of an iron article?

  1. APresence of dissolved in the water film on the surface
  2. BKeeping the article in pure water from which dissolved oxygen has been completely removed
  3. CKeeping the article in contact with a piece of copper in moist air
  4. DCoating the article with a layer of zinc

Answer: A, C

Rusting is an electrochemical process needing water, oxygen and conduction of ions. Dissolved electrolytes such as raise the conductivity of the water film and speed up the cell, so (A) increases rusting. Contact with a less active metal (Cu) makes iron the anode of a galvanic couple, so (C) increases rusting. Without oxygen the cathodic reaction cannot occur, so (B) does not increase rusting, and zinc coating protects iron sacrificially, so (D) decreases it.
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