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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ec173

Consider the cathodic protection of a buried iron pipeline. Given , , . Which statements are correct?

  1. AA block of copper connected to the pipeline would act as a sacrificial anode
  2. BIn impressed-current protection the pipeline is connected to the negative terminal of a DC source so that it becomes a cathode
  3. CA zinc block connected to the pipeline is oxidised in preference to iron because is more negative than
  4. DOn the protected iron surface in aerated neutral soil water, the main cathodic reaction is

Answer: B, C, D

Copper has a higher reduction potential than iron, so in a Fe-Cu couple iron is the anode and corrodes faster; (A) is wrong. Connecting the pipe to the negative terminal pushes electrons into it and makes it the cathode, which prevents ; (B) correct. Zinc, with the more negative potential, is the anode of the Zn-Fe couple and is consumed instead of iron; (C) correct. In neutral aerated water oxygen is reduced to hydroxide on the cathodic iron surface; (D) correct.
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