JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ec173
Consider the cathodic protection of a buried iron pipeline. Given E∘(FeX2+/Fe)=−0.44V, E∘(ZnX2+/Zn)=−0.76V, E∘(CuX2+/Cu)=+0.34V. Which statements are correct?
AA block of copper connected to the pipeline would act as a sacrificial anode
BIn impressed-current protection the pipeline is connected to the negative terminal of a DC source so that it becomes a cathode
CA zinc block connected to the pipeline is oxidised in preference to iron because E∘(ZnX2+/Zn) is more negative than E∘(FeX2+/Fe)
DOn the protected iron surface in aerated neutral soil water, the main cathodic reaction is OX2+2HX2O+4eX−4OHX−
Answer: B, C, D
Copper has a higher reduction potential than iron, so in a Fe-Cu couple iron is the anode and corrodes faster; (A) is wrong. Connecting the pipe to the negative terminal pushes electrons into it and makes it the cathode, which prevents FeFeX2+; (B) correct. Zinc, with the more negative potential, is the anode of the Zn-Fe couple and is consumed instead of iron; (C) correct. In neutral aerated water oxygen is reduced to hydroxide on the cathodic iron surface; (D) correct.