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JEE Main levelSingle correct optionDifficulty 2 of 3ec169

According to the electrochemical theory of rusting, at anodic spots and at cathodic spots . Which statement is correct?

  1. AOxidation of iron takes place at the cathodic spots
  2. BThe ions needed at the cathode come mainly from dissolved (carbonic acid) in the water film
  3. CRusting is faster when dissolved oxygen is removed from the water film
  4. DRust is deposited exactly at the anodic spot where iron dissolves

Answer: B

Iron is oxidised at the anodic spots, so (A) is wrong. Oxygen is the oxidant at the cathode, so removing it slows rusting, (C) wrong. The formed diffuses and meets and away from the anode, so rust appears between the anodic and cathodic regions, not exactly on the anode, (D) wrong. The in the thin water film comes mainly from dissolved () and other acidic impurities, so (B) is correct.
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