JEE Main levelSingle correct optionDifficulty 2 of 3ec162
A hydrogen-oxygen fuel cell operates at a terminal voltage of 0.72V. The electrical work obtained when 2.0mol of HX2 is consumed is (F=96500Cmol−1)
A69.5kJ
B139kJ
C278kJ
D556kJ
Answer: C
Each HX2 gives 2 electrons (HX22HX++2eX− or HX2+2OHX−2HX2O+2eX−), so 2.0molHX2 passes 4.0mol of electrons. Work =nFE=4.0×96500×0.72=2.78×105J=278kJ. Option (B) forgets that each HX2 gives two electrons.