JEE Main levelSingle correct optionDifficulty 2 of 3df180
Match the ions in Column I with their 4f configurations in Column II.
Column I: P = CeX3+, Q = EuX3+, R = GdX3+, S = YbX3+.
Column II: 1 = 4f1, 2 = 4f6, 3 = 4f7, 4 = 4f13.
AP-1, Q-3, R-2, S-4
BP-1, Q-2, R-4, S-3
CP-1, Q-2, R-3, S-4
DP-2, Q-1, R-3, S-4
Answer: C
Ce (Z = 58) is 4f15d16s2, so CeX3+ is 4f1. Eu (63) is 4f76s2, so EuX3+ is 4f6. Gd (64) is 4f75d16s2, so GdX3+ is 4f7. Yb (70) is 4f146s2, so YbX3+ is 4f13. The mapping is P-1, Q-2, R-3, S-4.