JEE Main levelSingle correct optionDifficulty 2 of 3df177
In acidic solution CeX4+ is a strong oxidising agent even though it has the stable 4f0 configuration. The best explanation is that
ACeX4+ has 4f14 configuration
BCeX4+ has a half-filled 4f subshell that it wishes to complete
CCeX4+ has a very small ionisation enthalpy
DCeX3+ is the characteristic stable oxidation state of lanthanoids, so CeX4+ tends to gain an electron
Answer: D
Reduction CeX4++eX−CeX3+ gives the +3 state, which is the most stable one for lanthanoids because of favourable hydration and lattice enthalpy. This stability, not the 4f0 configuration, drives the strong oxidising power. CeX4+ has 4f0, not half-filled or full.