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JEE Main levelSingle correct optionDifficulty 2 of 3df177

In acidic solution is a strong oxidising agent even though it has the stable configuration. The best explanation is that

  1. A has configuration
  2. B has a half-filled subshell that it wishes to complete
  3. C has a very small ionisation enthalpy
  4. D is the characteristic stable oxidation state of lanthanoids, so tends to gain an electron

Answer: D

Reduction gives the state, which is the most stable one for lanthanoids because of favourable hydration and lattice enthalpy. This stability, not the configuration, drives the strong oxidising power. has , not half-filled or full.
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