JEE Main levelSingle correct optionDifficulty 2 of 3df063
Assertion (A): MnX3+ is a much stronger oxidising agent than FeX3+ in aqueous solution.
Reason (R): Reduction of MnX3+ gives the stable half-filled d5 ion MnX2+, whereas FeX3+ (d5) would be reduced to the less stable d6 ion FeX2+.
ABoth Assertion and Reason are true and the Reason is the correct explanation of the Assertion
BBoth Assertion and Reason are true but the Reason is not the correct explanation of the Assertion
CAssertion is true but Reason is false
DAssertion is false but Reason is true
Answer: A
E∘(MnX3+/MnX2+)=+1.57V is much larger than E∘(FeX3+/FeX2+)=+0.77V, so A is true. MnX3+ is d4 and becomes d5 on reduction, while FeX3+ is already d5; this explains the difference, so R is true and explains A.